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Manganese and Iron Coordination Complexes for Biological Imaging and Oxidative Catalysis
(2014-04-23)
The ligand N,N’-bis(2-pyridylmethyl)-bis(ethylacetate)-1,2-ethanediamine (debpn)
coordinates divalent transition metal ions in either a pentadentate or hexadentate fashion. The coordination number correlates with the ionic ...
Structure, dynamics and interaction study of Glutaminase Interacting Protein (GIP) and its complex with Glutaminase L and Brain-specific Angiogenesis Inhibitor 2 (BAI2) peptide and characterization of subunit A of Heterodisulfide Reductase (HdrA) from Methanothermobacter marburgensis
(2013-07-30)
Glutaminase interacting protein (GIP) is a 124 amino acid long protein containing a single PDZ domain. This protein intersects a number of important biological pathways. In many of these pathways, the mechanism of function ...
Investigations into 5ꞌ-Extended 3-Deazaaristeromycin Derivatives
(2014-05-02)
Nucleosides have provided a plentiful source in structural leads in antiviral drug discovery. Included in this class of compounds are the carbocyclic nucleosides, which because of the presence of a cyclopentyl moiety, offer ...
The Extension of Colloid Chemistry from Aqueous to Non-Aqueous Media with Application to Nanofluid Research
(2011-11-17)
Nanofluids are colloids whose design is specific to the study and application of heat transfer systems. Metals typically have thermal conductivities which are several times higher than that of traditional cooling liquids ...
Application of Novel Nanoscale Materials and Advanced Electrochemical Techniques in Heterogeneous Catalysis and Fabrication of Combinatorial Material Libraries by Bipolar Electrodeposition
(2011-09-08)
The advancements in the electrochemical technologies combined with the introduction of novel materials makes our lives a lot better. This work has two major divisions: (1) development of better electrocatalysts for fuel ...
Biophysical characterization of ligand binding and release of Anthereae polyphemus Pheromone Binding Protein 1 (ApolPBP1) and Exploring the nickel proteome
(2013-08-07)
In moths, pheromone binding proteins (PBPs) transport the hydrophobic pheromone molecules to the membrane-bound receptors across the aqueous sensillar lymph to trigger the neuronal response. We showed here that, recombinant ...
The Synthesis and Practical Applications of Novel N-Halamine Biocides
(2009-02-23)
A novel set of N-halamine siloxane precursors were synthesized for the purpose of coating various substrates to determine the factors, which are the most dominant influences of the overall stability of the newly modified ...
Chemically Modified Electrodes: A Supramolecular Assembly Approach
(2009-02-23)
The main objective of this dissertation is to design and study new superamolecular assemblies for membrane separation, sensing and catalysis applications. Three types of supramolecular assemblies will be addressed including ...
A Computational Mechanistic Study of an Aza-Michael Addition and a Paal-Knorr Reaction
(2015-01-13)
Computational chemistry is a rapid growing branch of chemistry that seeks to interpret chemical problems and predict chemical phenomena using mathematical approximations and computer programs. In the present work, we ...
Copper(II)-Mediated 2-Quinoxalinol Salens in Alcohol Oxidation and C-H Activation: A Greener Approach
(2014-07-11)
Reduction of waste production in chemical processes is the idea of greener chemistry by using less toxic or benign methods and eliminating purification steps. Because of this, using a catalytic rather than stoichiometric ...