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Browsing by Author "Chen, Ming"

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THE DEVELOPMENT OF BIFUNCTIONAL ALLYLBORONATE REAGENTS FOR STEREOSELECTIVE CARBONYL ALLYLBORATION 

Liu, Jiaming (2023-07-17)
CHAPTER 1 The synthesis of a bifunctional allylboron reagent via Ni-catalyzed borylation of allylic acetate is developed. Subsequent allylation of aldehydes, ketones and cyclic aldimines gave homoallylic alcohols and ...

Enantioselective synthesis of 1,6-dihydropyridines with application to natural product synthesis; Racemic total synthesis of the fungal metabolite collybolide 

Spurlin, Sean (2023-08-09)  ETD File Embargoed
Azaheterocycles, a common feature of many bioactive natural products, are still challenging motifs to construct in an asymmetric fashion. Dihydropyridines are advantageous intermediates in the synthesis of such heterocycles, ...

Enantioselective synthesis of 1,6-dihydropyridines with application to natural product synthesis; Racemic total synthesis of the non-nitrogenous opioid collybolide 

Spurlin, Sean (2023-08-06)  ETD File Embargoed
Azaheterocycles, a common feature of many bioactive natural products, are still challenging motifs to construct in an asymmetric fashion. Dihydropyridines are advantageous intermediates in the synthesis of such heterocycles, ...

Regio- and Enantioselective Synthesis of N-alkyl 1,2- and 1,6-dihydropyridines through Rhodium-Catalyzed Nucleophilic Dearomatization 

Robinson, Donovan (2022-07-28)
Nonaromatic nitrogen heterocycles, particularly the ones containing one or multiple stereogenic centers, are common structural motifs in bioactive natural products and continue to be challenging synthetic targets. The ...