Browsing by Author "Livant, Peter D."

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An Approach to Bis(amino Acid)s Utilizing Dimethyl 2,4-bis(diazo)-3-oxoglutarate and Studies of Tris(2,6-dihydroxyphenyl)e, E = B, P.

Guan, Lirui (2005-12-15)

When treated with a diazo transfer agent, dimethyl 3-oxoglutarate afforded a high yield of the bis(diazo) compound dimethyl 2,4-bis(diazo)-3-oxoglutarate, 33. The bis(diazo) compound, catalyzed by Rh2(OAc)4, reacted with ...

Mechanism of the Outer-sphere Oxidation of Aqueous L-cysteine and of Iodide in Acetonitrile by a Series of Iron(III) Complexes

Wang, Xiaoguang (2007-05-15)

Trace copper catalysis was observed in the oxidation of L-cysteine by [Fe(bpy)2(CN)2]+ and [Fe(bpy)(CN)4]- in anaerobic aqueous solution. The copper catalysis was effectively inhibited with the addition of dipicolinate ...